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Entropy of Nanostructures: Topological Effects on Schottky Vacancies Concentration in Graphenic Bidimensional HC(N) Lattices
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Author(s): Ottorino Ori (Actinium Chemical Research, Italy & West University of Timişoara, Romania), Franco Cataldo (Actinium Chemical Research, Italy)and Mihai V. Putz (West University of Timişoara, Romania & Research and Development National Institute for Electrochemistry and Condensed Matter (INCEMC) Timişoara, Romania)
Copyright: 2017
Pages: 15
Source title:
Sustainable Nanosystems Development, Properties, and Applications
Source Author(s)/Editor(s): Mihai V. Putz (West University of Timişoara, Romania & Research and Development National Institute for Electrochemistry and Condensed Matter (INCEMC) Timişoara, Romania)and Marius Constantin Mirica (Research and Development National Institute for Electrochemistry and Condensed Matter (INCEMC) Timişoara, Romania)
DOI: 10.4018/978-1-5225-0492-4.ch016
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Abstract
Recent advances in graphene studies deal with the influence of structural defects on graphene chemical, electrical, magnetic and mechanical properties. Here the complex mechanisms leading to the formation of clusters of vacancies in 2D honeycomb HD lattices are described by a pure topological point of view, aiming to correlate the variation of specific topological invariants, sensible to vacancy concentration, to the structural evolution of the defective networks driven by the topo-thermodynamical Gibbs free energy. Interesting predictions on defect formation mechanisms add details on the topological mechanisms featured by the graphenic structures with defects. Future roles of bondonic particles in defective HD materials are also envisaged.
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