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Polyoxometalates-Based Nanocatalysts and Their Efficiency for Production of Sulfur-Free Diesel
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Author(s): Diana Julião (LAQV/REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Portugal), Susana Ribeiro (LAQV/REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Portugal), Baltazar de Castro (LAQV/REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Portugal), Luís Cunha-Silva (LAQV/REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Portugal)and Salete S. Balula (LAQV/REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, Portugal)
Copyright: 2020
Pages: 42
Source title:
Nanocomposites for the Desulfurization of Fuels
Source Author(s)/Editor(s): Tawfik Abdo Saleh (King Fahd University of Petroleum and Minerals, Saudi Arabia)
DOI: 10.4018/978-1-7998-2146-5.ch004
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Abstract
Polyoxometalates have been demonstrated to be efficient catalysts for the activation of oxidants in desulfurization processes. Successful results on desulfurization using polyoxometalates and hydrogen peroxide to desulfurize model oils and liquid fuels were reported and can be found in the literature. The desulfurization is an actual subject with notable interest for refineries and fuel cost, and consequently, it is important to focus the scientific community to work in desulfurization technology in order to develop catalytic systems based on polyoxometalates capable to be reused, stable, efficient, and selective. Therefore, the main goal is the design of heterogeneous polyoxometalate based catalysts. This chapter pretends to inform the research society about the scientific directions that have been taken using heterogeneous polyoxometalate catalysts in oxidative desulfurization of simulated and real liquid fuels. In addition, future perspectives are proposed to cover the actual needs of this area.
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